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Tunable In Situ 3D-Printed PVDF-TrFE Piezoelectric Arrays.

Alec Ikei1, James Wissman1, Kaushik Sampath1

  • 1Naval Research Laboratory, 4555 Overlook Ave SW, Washington, DC 20375, USA.

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Summary
This summary is machine-generated.

This study introduces in situ 3D printing and poling of poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE), achieving high piezoelectric performance for advanced pressure sensors. This novel method significantly enhances sensitivity and accuracy in 3D-printed sensor arrays.

Keywords:
3D printingPVDFPVDF-TrFEsensorssmart materials

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Area of Science:

  • Materials Science
  • Polymer Science
  • Additive Manufacturing

Background:

  • Poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) is preferred over PVDF for piezoelectric applications due to superior performance without significant mechanical strain.
  • Existing methods for poling piezoelectric polymers can be complex and may not integrate seamlessly with 3D printing processes.

Purpose of the Study:

  • To present a novel in situ 3D printing and poling technique for PVDF-TrFE.
  • To demonstrate enhanced piezoelectric performance and explore applications in high-sensitivity pressure sensors and sensor arrays.

Main Methods:

  • Developed an integrated 3D printing and in situ poling process for PVDF-TrFE.
  • Fabricated and tested 3D-printed PVDF-TrFE samples for piezoelectric coefficient (d33).
  • Compared in situ poled samples with those prepared using ex situ corona poling.

Main Results:

  • Achieved a d33 piezoelectric performance of up to 18 pC N-1, an order of magnitude higher than previously reported in situ poled polymer piezoelectrics.
  • Demonstrated the capability of in situ poled sensors in a fully 3D-printed five-element sensor array.
  • Confirmed superior performance of in situ poled samples compared to ex situ corona poled samples.

Conclusions:

  • The in situ 3D printing and poling of PVDF-TrFE offers a significant advancement for creating highly sensitive and accurate pressure sensors.
  • This technique expands the design possibilities for complex, functional 3D-printed sensor arrays.
  • The developed method accelerates the development of next-generation piezoelectric devices through integrated additive manufacturing and poling.