A Lamellar MXene (Ti₃ C₂ T_x )/PSS Composite Membrane for Fast and Selective Lithium-Ion Separation

A two-dimensional (2D) laminar membrane with Li⁺ selective transport channels is obtained by stacking MXene nanosheets with the introduction of poly(sodium 4-styrene sulfonate) (PSS) with active sulfonate sites, which exhibits excellent Li⁺ selectivity from ionic mixture solutions of Na⁺ , K⁺ , and Mg²⁺ . The Li⁺ permeation rate through the MXene@PSS composite membrane is as high as 0.08 mol m^-2  h^-1 , while the Li⁺ /Mg²⁺ , Li⁺ /Na⁺ , and Li⁺ /K⁺ selectivities are 28, 15.5, and 12.7, respectively. Combining the simulation and experimental results, we further confirm that the highly selective rapid transport of partially dehydrated Li⁺ within subnanochannels can be attributed to the precisely controlled interlayer spacing and the relatively weaker ion-terminal (-SO₃ ^- ) interaction. This study deepens the understanding of ion-selective permeation in confined channels and provides a general membrane design concept.