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Published on: April 22, 2016
Artificial plant cell walls as multi-catalyst systems for enzymatic cooperative asymmetric catalysis in non-aqueous
Luca Deiana1, Abdolrahim A Rafi, Veluru Ramesh Naidu
1Department of Natural Sciences, Mid Sweden University, Holmgatan 10, 85 179 Sundsvall, Sweden. Armando.Cordova@miun.se.
Abstract:
The assembly of cellulose-based artificial plant cell wall (APCW) structures that contain different types of catalysts is a powerful strategy for the development of cascade reactions. Here we disclose an APCW catalytic system containing a lipase enzyme and nanopalladium particles that transform a racemic amine into the corresponding enantiomerically pure amide in high yield via a dynamic kinetic resolution.
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