Biowaste hydrothermal carbonization aqueous product application in rice paddy: Focus on rice growth and ammonia...

Hydrothermal carbonization (HTC) is known as a green biomass conversion technology. However, it often suffers from the issue of disposing hydrothermal carbonization aqueous products (HCAP). Based on the characterization and composition of acidic HCAP, a rice paddy soil column experiment was conducted to observe the effects of HCAP on ammonia (NH₃) volatilization form paddy soil and rice yield. The experiment was designed with five treatments. HCAPs were produced at 220 °C and (SHC220-L) and 260 °C (SHC260-L) derived from poplar sawdust, HCAP produced at 220 °C (WHC220-L) and 260 °C (WHC260-L) derived from wheat straw, and a control group without HCAP application (termed CKU hereafter). The results showed that HCAP treatments increased the rice yield by 4.30%-26.0% compared to CKU. HACPs prepared at lower temperatures (SHC220-L and WHC220-L) mitigated the cumulative NH₃ volatilization by 11.2% and 7.6%, respectively, and mitigated yield-scale NH₃ volatilization (cumulative NH₃ volatilization/total yield) by 14.2% ∼ 22.4%. HCAP significantly improved the N use efficiency of rice. We found that the NH₃ volatilization was related to NH₄⁺-N concentration and pH of surface water, soil TOC and NH₄⁺-N oxidation functional genes. This study implied that HCAP could be potentially used as a liquid fertilizer, which will be a potential substitute for chemical N fertilizers. There is still a long way before HCAP can be applied in full-scale for N fertilizer reduction and waste recycle.