Heterostructure engineering of ultrathin SnS₂/Ti₃C₂T_x nanosheets for high-performance potassium-ion batteries

Layered metal sulfides are considered as promising candidates for potassium ion batteries (KIBs) owing to the unique interlayer passages for ion diffusion. However, the insufficient electronic conductivity, inevitable volume expansion, and sulfur loss hinder the promotion of K-ion storage performance. Herein, few-layered Ti₃C₂T_x nanosheets were selected as the multi-functional substrate for cooperating few-layered SnS₂ nanosheets, constructing SnS₂/Ti₃C₂T_x hetero-structural nanosheets (HNs) with the thickness as thin as about 5 nm. In this configuration, the formed Ti-S bonds provide robust interaction between SnS₂ and Ti₃C₂T_x nanosheets, which hinders the agglomeration of SnS₂ and the restack of Ti₃C₂T_x, endowing the hybrid material with robust nanostructure. Thus, the shortcomings of the SnS₂ anode are muchly relieved. In this way, the as-prepared SnS₂/Ti₃C₂T_x HNs electrode delivers reversible capacities of 462.1 mAh g^-1 at 0.1 A g^-1 and 166.1 mAh g^-1 at 2.0 A g^-1, respectively, and a capacity of 85.5 mAh g^-1 is remained even after 460 cycles at 2.0 A g^-1. These results are superior to those of the counterpart electrode, confirming aggressive promotion of K-ion storage performance of SnS₂ anode brought by the cooperation of Ti₃C₂T_x, and presenting a reliable strategy to improve the electrochemical performance of sulfide anodes.