Cu₂O/TiO₂ decorated on cellulose nanofiber/reduced graphene hydrogel for enhanced photocatalytic activity and its antibacterial applications

Photocatalysis has gained attention as a viable wastewater remediation technique. However, the difficulty of recovering powder-based photocatalyst has often become a major limitation for their on-site practical application. Herein, we report on the successful in-situ preparation of a novel three-dimensional (3D) photocatalyst consisting of Cu₂O/TiO₂ loaded on a cellulose nanofiber (CNF)/reduced graphene hydrogel (rGH) via facile hydrothermal treatment and freeze-drying. The 3D macrostructure not only provides a template for the anchoring of Cu₂O and TiO₂ but also provides an efficient electron transport pathway for enhanced photocatalytic activity. The results showed that the Cu₂O and TiO₂ were uniformly loaded onto the aerogel framework resulting in the composites with large surface area with exposed actives sites. As compared to bare rGH, CNF/rGH, Cu₂O/CNF/rGH and TiO₂/CNF/rGH, the Cu₂O/TiO₂/CNF/rGH showed improved photocatalytic activity for methyl orange (MO) degradation. MO degradation pathway is proposed based on GC-MS analysis. The enhanced photoactivity can be attributed to the charge transfer and electron-hole separation from the synergistic effect of Cu₂O/TiO₂ anchored on CNF/rGH. In terms of their anti-bacterial activity towards Staphylococcus aureus and Escherichia coli, the synergistic effect of the Cu₂O/TiO₂ anchored on the CNF/rGH framework showed excellent activity towards the bacteria.