A Highly Selective and Sensitive Colorimetric Chemosensor for the Detection of Hydrogen Sulfide: A Real-time...

Calorimetric chemosensors are found to be advantageous sensing systems due to their simplicity and favorable responsive properties. Although some colorimetric probes have been reported to detect hydrogen sulfide (H₂ S), the creation of rapid, highly selective and sensitive probes for the detection of H₂ S remains a challenging target. In this work, we established dinitrosulphonamide decorated phenanthridine and 2,4-dinitro-N-(4-(7,8,13,14-tetrahydrodibenzo[a, i]phenanthridin-5-yl)phenyl)benzenesulfonamide (PHSH), for the calorimetric detection of H₂ S. H₂ S-triggered thiolysis of PHSH resulted in a marked absorption enhancement alongside a visual color change from colorless to dark yellow. The result indicated that the chemosensor showed high sensitivity and selectivity with a fast response of less than 10 s with a detection limit as low as 6.5 nM. The chemosensor reaction mechanism with H₂ S was studied by UV-vis, ¹ H NMR, mass and HPLC analysis. In addition, the chemosensor has been used for the determination of H₂ S in many real-time samples.