Related Experiment Video
Updated: Oct 24, 2025

Optical Trap Loading of Dielectric Microparticles In Air
Published on: February 5, 2017
Excess wings and asymmetric relaxation spectra in a facilitated trap model
Camille Scalliet1, Benjamin Guiselin2, Ludovic Berthier2
1Department of Applied Mathematics and Theoretical Physics, University of Cambridge, Wilberforce Road, Cambridge CB3 0WA, United Kingdom.
Abstract:
In a recent computer study, we have shown that the combination of spatially heterogeneous dynamics and kinetic facilitation provides a microscopic explanation for the emergence of excess wings in deeply supercooled liquids. Motivated by these findings, we construct a minimal empirical model to describe this physics and introduce dynamic facilitation in the trap model, which was initially developed to capture the thermally activated dynamics of glassy systems. We fully characterize the relaxation dynamics of this facilitated trap model varying the functional form of energy distributions and the strength of dynamic facilitation, combining numerical results and analytic arguments. Dynamic facilitation generically accelerates the relaxation of the deepest traps, thus making relaxation spectra strongly asymmetric, with an apparent "excess" signal at high frequencies. For well-chosen values of the parameters, the obtained spectra mimic experimental results for organic liquids displaying an excess wing. Overall, our results identify the minimal physical ingredients needed to describe excess processes in the relaxation spectra of supercooled liquids.
Related Concept Videos
Atomic Nuclei: Nuclear Relaxation Processes
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
NMR Spectrometers: Resolution and Error Correction

