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Updated: Oct 23, 2025
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
Tunable White-Light Emissions of Azapyrene Derivatives with Cucurbit[n]uril Hosts in Aqueous Solution
Guangtan Fan1, Xiang Yu1, Xie Han1,2
1The State Key Laboratory of Refractories and Metallurgy, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China.
Abstract:
Cucurbit[n]uril (CB[n])-mediated assembly of π-conjugated azapyrene derivatives with rigid aromatic rings as bridging units into optically tunable complexes is reported. Due to the hindrance of rotation of diazapyrene moieties and the enhancement of intramolecular charge transfer of chromophore guests within the cavity of the CB[8] host, color tuning including white-light emission was easily achieved by introducing CB[8] into the guest aqueous solution, therefore suggesting a feasible strategy for the creation of tunable white-light emission materials through CB[n]-based host-guest interactions.
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