Interconnected magnetic carbon@Ni_xCo_1-xFe₂O₄ nanospheres with core-shell structure: An efficient and thin...

The applications of cobalt ferrite and nickel ferrite composite materials on electromagnetic (EM) wave absorption are the research hotspot currently. However, the systematical comparison study between these two ferrites composites have rarely been carried out. Thus, the EM wave absorption performance of interconnected carbon@Ni_xCo_1-xFe₂O₄ composites with core-shell structures were investigated comprehensively in this work. A series of magnetic nanospheres including NiFe₂O₄, cobalt-doped nickel ferrite, nickel-cobalt ferrite, nickel-doped cobalt ferrite and CoFe₂O₄ were synthesized firstly, and then uniformly encapsulation by carbon rendered the corresponding C@Ni_xCo_1-xFe₂O₄ composites nanospheres. Synthesis reactions involved for C@Ni_xCo_1-xFe₂O₄ formation were investigated in detail, and afterwards their magnetic behavior, EM wave absorption performance and absorbing mechanism were thoroughly explored and analyzed. Results show that when nickel is dominant element and cobalt is doping element (Ni_0.75Co_0.25Fe₂O₄), the composite nanosphere exhibits optimum EM wave absorption performance. When the sample thickness is just 1.9 mm, its RL_min value can reach -51 dB, and the corresponding EAB width is 3.3 GHz. The synthesized C@Ni_0.75Co_0.25Fe₂O₄ can be qualified as an efficient and thin electromagnetic wave absorber, which is mainly attributed to its special structure, fair electromagnetic matching and impedance matching.