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Organic Persistent Luminescent Materials: Ultralong Room-Temperature Phosphorescence and Multicolor-Tunable Afterglow
Renjie Chen1, Yan Guan2, Hailong Wang1
1Key Lab of Environment-friendly Chemistry and Application in Ministry of Education, and Key Laboratory of Advanced Functional Polymer Materials of Colleges, Universities of Hunan Province and College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, China.
Abstract:
Organic persistent luminescent materials have attracted special attention due to their significant applications in optoelectronics, sensors, and security technology areas. In this work, a series of organic compounds (1-4) with twisted electron donor-acceptor structures are successfully designed and synthesized, and then the resultant compounds are dissolved in methyl methacrylate (MMA), and afterward, in situ polymerization realizes single-molecular organic room-temperature phosphorescent (RTP) materials (P1-P4). All RTP materials show long lifetime, especially P2 exhibits ultralong lifetime of 1.51 s. When the compounds are grown into single crystals, multicolor-tunable afterglow is obtained at different delay times due to the dual emission of phosphorescence and delayed fluorescence, which is promising to be applied in high-level anticounterfeiting.
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