Targeted degradation of refractory organic compounds in wastewaters based on molecular imprinting catalysts

Efficient removal of low-concentration refractory pollutants is a crucial problem to ensuring water safety. The use of heterogeneous catalysis of molecular imprinting technology combined with traditional catalysts is a promising method to improve removal efficiency. Presently, the research into molecular imprinting targeting catalysts focuses mainly on material preparation and performance optimization. However, more researchers are investigating other applications of imprinting materials. This review provides recent progress in photocatalyst preparation, electrocatalyst, and Fenton-like catalysts synthesized by molecular imprinting. The principle and control points of target catalysts prepared by precipitation polymerization (PP) and surface molecular imprinting (S-MIP) are introduced. Also, the application of imprinted catalysts in targeted degradation of drugs, pesticides, environmental hormones, and other refractory pollutants is summarized. In addition, the reusability and stability of imprinted catalyst in water treatment are discussed, and the possible ecotoxicity risk is analyzed. Finally, we appraised the prospects, challenges, and opportunities of imprinted catalysts in the advanced oxidation process. This paper provides a reference for the targeted degradation of refractory pollutants and the preparation of targeted catalysts.