Metal-free 2D/2D C₃N₅/GO nanosheets with customized energy-level structure for radioactive nuclear wastewater...

How to efficiently treat radioactive uranium-containing nuclear wastewater is one of the significant challenges to ensure the safety of nuclear technology and to avoid environmental pollution. Here we firstly prepare the metal-free 2D/2D C₃N₅/GO nanosheets, and customize a type-II heterojunction based on the band bending theory to achieve enhanced uranium extraction capacity via synergistic adsorption photoreduction engineering. The structure of C₃N₅ is explained by electron energy loss spectroscopy and synchrotron-based near-edge X-ray absorption fine structure. And C₃N₅ with larger π-conjugated structure expands the light response range to 747 nm, which is about 1.67 times that of C₃N₄. Further, we also use density functional theory to prove the existence of alternating energy levels so that photogenerated electrons could be continuously injected into the surface of GO to ensure the effective separation of electron-hole pairs and increase the material activity. The results show that the removal ratio of uranium by 2D/2D C₃N₅/GO heterojunction is achieved as high as 96.1% even at a low uranium concentration of 10 ppm, and reached 93.4% after exposure to gamma-ray. This work will lay a foundation for customizing the energy band structure of nonmetal-based 2D/2D nanohybrids and enriching uranium-containing wastewater through adsorption photoreduction engineering in the future.