Promotional effect of ZrO₂ and WO₃ on bimetallic Pt-Pd diesel oxidation catalyst

Diesel oxidation catalysts Pt-Pd-(y)ZrO₂-(z)WO₃/CeZrO_x-Al₂O₃ with total Pt & Pd loading of only 0.68 wt.% were prepared and investigated for oxidation activity and stability of CO, C₃H₆, and NO. Introduction of ZrO₂ greatly improved low-temperature activities and retained stability especially for CO and C₃H₆ oxidation after treated at 800 °C. With the optimal loading amount of 6 wt% ZrO₂, 2 wt% WO₃ was introduced to the system and showed higher activity. Reaction temperature for 50% CO and C₃H₆ conversion declined to 160 and 181 °C, and the maximal NO conversion increased to 50%. By using XRD, TEM, CO chemisorption, XPS, and H₂-TPR analysis, it was found that ZrO₂ could inhibit aggregation of Pt and Pd, improve metal dispersion, and increase surface-chemisorbed oxygen after high-temperature treatment, accounting for promoted performance. Also, there were more reducible oxide species in ZrO₂-doped catalysts. ZrO₂ could induce reduction of noble metal oxides and surface ceria by weakening Pt-O-Ce interaction, which increased the ability to dissociate H₂ and spillover effect of dissociated hydrogen to ceria. Doping WO₃ increased metal dispersion of fresh samples and brought more Pt⁰ species that were active sites for oxidation reactions. Thus, ZrO₂ and WO₃ could be effective additives for oxidation catalysts to synergistically improve their activities and thermal stability.