Synthesizing Various Organic Polyacid Compounds for Modifying Forward Osmosis Membranes to Enhance Separation...

In order to overcome the challenges of low permeate flux (J_p) and the accompanying reverse solute flux (J_S) during the forward osmosis (FO) membrane separation process, we synthesized four hybrid materials of polyacid-based organic compounds and incorporated them into the selective polyamide (PA) layer to make novel thin-film nanocomposite (TFN) FO membranes. The J_p and J_S of each membrane were evaluated and used along with membrane selectivity (J_p/J_S) as indicators of membrane separation performance. The fabricated and modified membranes were also characterized for ridge and valley surface morphologies with increasing hydrophilicity and finger-shaped parallel channels in the PSf substrate. Moreover, two highly hydrophilic nanoparticles of graphene oxide (GO) and titanium oxide (TiO₂) were introduced with the hybrid materials for PA modification, which can further enhance the J_p of the TFN membranes. The highest J_p of the TFN membranes achieved 12.1 L/m²-h using 0.1% curcumin-acetoguanamine @ cerium polyacid (CATCP) and 0.0175% GO. The characteristic peaks of the hybrid materials were detected on the membrane surface using attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, evidencing successful incorporation of the hybrid materials during membrane modification. Here, we present the novel TFN membranes using hybrid materials for separation applications. The reactions for synthesizing the hybrid materials and for incorporating them with PA layer are proposed.