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Updated: Oct 22, 2025

Synthesis and Testing of Supported Pt-Cu Solid Solution Nanoparticle Catalysts for Propane Dehydrogenation
Published on: July 18, 2017
Effective stabilization of atomic hydrogen by Pd nanoparticles for rapid hexavalent chromium reduction and
Shanpeng Li1, Chunlei Liu2, Haijin Liu3
1School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China.
Abstract:
Atomic hydrogen (H*) plays a vital role in the synchronous redox of metallic ions and organic molecules. However, H* is extremely unstable as it is easily converted to hydrogen. Herein, we designed a novel strategy for the effective stabilization of H* to enhance its utility. The synthesized Pd nanoparticles grown on the defective MoS2 (DMS) of TiO2 nanowire arrays (TNA) (TNA/DMS/Pd) photocathode exhibited rapid Cr(VI) reduction (~95% in 10 min) and bisphenol A (BPA) oxidation (~97% in 30 min), with the kinetic constants almost 24- and 6-fold higher than those of the TNA photocathode, respectively. This superior performances could be attributed to: (i) the generated interface heterojunctions between TNA and DMS boosted the separation efficiencies of photogenerated electrons, thereby supplying abundant valance electrons to lower the overpotential to create a suitable microenvironment for H* generation; (ii) the stabilization of H* by Pd nanoparticles resulted in a significant increase in the yield of hydroxyl radical (•OH). This research provides a new strategy for the effective utilization of H* toward rapid reduction of heavy metals and synchronous oxidation of the refractory organics.
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