Carbon stability and mobility of ball milled lignin- and cellulose-rich biochar colloids

Numerous studies have explored the transport mechanism of biochar colloids in porous medium. However, the effect of feedstock biopolymer compositions and pyrolytic temperature on carbon stability and mobility of biochar colloids is limited. This study prepared four ball milled biochar colloids pyrolyzed from lignin-rich pinewoods and cellulose-rich corn stalks under 300 °C and 500 °C (termed as PW300, PW500, CS300, CS500) and analyzed their differences in the chemical stability and transport behaviors. The results indicated that high contents of lignin in biomass and pyrolytic temperature could enhance the compact aromatic structures of biochar colloids characterized by the elemental composition, FTIR, ¹³C NMR and XRD analyses. Therefore, PW500 with the strongest chemical stabilities (least C loss of 13%), electronegativity (-44.9 mV vs. -41.6-28.3 mV) and smallest hydrodynamic diameter (608.7 nm vs. 622-997.2 nm) was obtained under ball milling. Moreover, both the critical coagulation concentrations (CCC) and the maximum relative effluent concentration (C/C₀) with the NaCl ionic strength of 1 mM were demonstrated to be in the increase order of CS300 (76.1 mM, 70%) < PW300 (183.1 mM, 78%) < CS500 (363.9 mM, 89%) < PW500 (563.1 mM, 95%), which suggested stronger colloidal stability and mobility of PW biochar colloids than those of CS biochar colloids. In addition, the C/C₀ for CS300, PW300 and CS500 were about 7.3%-36% lower than that for PW500 with the NaCl ionic strength increasing to 50 mM indicated the notable superiority in the mobility of PW500. These findings can provide new insights toward understanding the transformation and migration, and evaluating the environmental risk of biochar colloids.