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Gas Sensor Array Using a Hybrid Structure Based on Zeolite and Oxide Semiconductors for Multiple Bio-Gas Detection
Jongyoon Park1, Hitoshi Tabata1
1Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
ACS Omega
|September 2, 2021
Summary
This study developed a novel bio-gas sensor using metal-oxide semiconductors and zeolites. The hybrid sensor array successfully identified different volatile organic compounds, regardless of their concentration.
Area of Science:
- Materials Science
- Chemical Sensing
- Nanotechnology
Background:
- Semiconductor-type gas sensors utilizing metal-oxide semiconductors and porous zeolite materials show promise for bio-gas detection.
- Previous research demonstrated bio-gas sensing capabilities using zeolites and tungsten oxide (WO3) nanoparticles, often with a separate gas concentrator.
- Porous molecular structures in gas concentrators can modify gas sensitivity, selectivity, and define sensor characteristics.
Purpose of the Study:
- To investigate the properties of a gas sensor array composed of WO3 nanoparticles coated with zeolites.
- To evaluate the sensor array's ability to discriminate between different volatile organic compounds (VOCs) based on zeolite interactions.
- To determine if zeolite-modified hybrid sensors can identify VOCs independent of their concentration.
Main Methods:
- Fabrication of a three-sensor array using WO3 nanoparticles coated with zeolites exhibiting varied gas molecule adsorption/desorption properties.
- Testing the sensor array with four different volatile organic compounds at varying concentrations.
- Analysis of sensor responses to determine compound discrimination capabilities.
Main Results:
- The zeolite-coated WO3 nanoparticle sensors demonstrated distinct responses to different VOCs.
- The combination of individual zeolite properties and hybrid sensor behavior enabled compound discrimination.
- The sensor array successfully differentiated volatile compounds even when concentration levels varied.
Conclusions:
- Zeolite-modified metal-oxide semiconductor sensors offer a viable platform for selective volatile organic compound detection.
- The developed hybrid gas sensor array can identify specific VOCs irrespective of their concentration.
- This approach holds potential for applications like electronic noses in bio-gas monitoring.

