A highly sensitive ratiometric fluorescent sensor for copper ions and cadmium ions in scallops based on nitrogen...

Based on the electrostatic interaction, we constructed a ratiometric fluorescence nanomixture of graphene quantum dots-gold nanoclusters (GQDs-AuNCs) for the quantitative detection of Cu²⁺ and Cd²⁺. When Cu²⁺ or Cd²⁺ was added into the reaction system, the fluorescence of GSH-AuNCs at 565 nm can be quenched by Cu²⁺ and enhanced by Cd²⁺ while the intensity of N-GQDs at 403 nm stayed constant. Under the optimized conditions, the fluorescence intensity ratio (I₅₆₅/I₄₀₃) of the GQDs-AuNCs system was proportional to the concentration of Cu²⁺ and Cd²⁺ in the range of 8×10^-8 mol/L-6×10^-6 mol/L and 1×10^-6 mol/L-4×10^-5 mol/L, respectively, with detection limits of 4.12×10^-9 mol/L and 9.43×10^-7 mol/L, respectively. In the presence of Cu²⁺ and Cd²⁺, the paper-based vision sensor would produce visible fluorescent color changes, which can be used for rapid detection on site. The method has been successfully applied to the determination of Cu²⁺ and Cd²⁺ in scallops with satisfactory results.