C₆₀-encapsulated TiO₂nanoparticles for selective and ultrahigh sensitive detection of formaldehyde

The current study concerns development of fullerene-C₆₀-encapsulated TiO₂nanoparticles hybrid for an efficient detection of volatile organic compounds (VOCs). The nanocomposite was synthesized via chemical route by using hydrated fullerene-C₆₀and sol-gel derived undopedp-type TiO₂nanoparticles. The nanocomposite was characterized morphologically and structurally comparing with pure C₆₀clusters and pure TiO₂nanoparticles as the reference materials. The average diameter of the C₆₀-encapsulated TiO₂nanoparticles was 150 nm whereas the average diameters of C₆₀clusters and pure TiO₂nanoparticles were 161 nm and 18 nm respectively. Therefore, all the materials were implemented in interdigitated electrode based planner structured sensors and tested towards multiple VOCs. However, C₆₀-TiO₂composite exhibited its natural selectivity towards formaldehyde with a very high sensitivity for the concentration range of 1-1000 ppm. C₆₀-encapsulated TiO₂nanoparticles depicted more than double response magnitude (117%) than the pure TiO₂nanoparticle (48%) and pure C₆₀particles (40%) and appreciably fast response/recovery (12 s/331 s) towards 100 ppm of formaldehyde at 150 °C. However, the efficient VOC sensing was achieved in C₆₀-encapsulated TiO₂sensors possibly due to the extreme reactive surface provided by the oxygen functionalized C₆₀and easy electronic exchange between ambient and the TiO₂nanoparticles through C₆₀layers. The combined properties of both C₆₀and TiO₂lead to the formation of a promising nanocomposite which provided better sensing characteristics than that of the pure materials.