Weyl semimetal orthorhombic Td-WTe₂as an electrode material for sodium- and potassium-ion batteries

Alkali metals such as sodium and potassium have become promising candidates for the next generation of monovalent-ion batteries. However, a challenge for these battery technologies lies in the development of electrode materials that deliver high capacity and stable performance even at high cycling currents. Here we study orthorhombic tungsten ditelluride or Td-WTe₂as an electrode material for sodium- (SIB) and potassium-ion batteries (KIB) in propylene carbonate (PC) based electrolyte. Results show that despite larger Shannon's radius of potassium-ions and their sluggish diffusion in Td-WTe₂due to higher overpotential, at 100 mA.g^-1KIB-half cells showed higher cycling stability and low capacity decay of 4% versus 16% compared to SIB-half cells. Likewise, in a rate capability test at 61^stcycle (at 50 mA.g^-1), the KIB-half cells yielded charge capacity of 172 mAh.g^-1versus 137 mAh.g^-1of SIB-half cells. The superior electrochemical performance of Td-WTe₂electrode material in KIB-half cells is explained based on the concept of Stokes' radius-smaller desolvation activation energy resulted in higher mobility of potassium-ions in PC-based electrolyte. In addition, the likely mechanisms of electrochemical insertion and extraction of Na- and K-ions in Td-WTe₂are also discussed.