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Updated: Oct 21, 2025

TiO2-coated Hollow Glass Microspheres with Superhydrophobic and High IR-reflective Properties Synthesized by a Soft-chemistry Method
Published on: April 26, 2017
Surface hybridization of π-conjugate structure cyclized polyacrylonitrile and radial microsphere shaped TiO2 for
Yachao Xu1, Hongsen Zhang1, Qi Liu2
1Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001, China; College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China; Key Laboratory of Marine Special Materials, Ministry of Industry and Information Technology, China.
Abstract:
It is still a challenge to obtain uranium (U) adsorbents with high selectivity, excellent cycle stability and excellent performance through design and synthesis. In this paper, the TiO2/CPAN-AO catalyst was prepared by the hydrothermal method combined with high temperature cyclization dehydrogenation. TiO2/CPAN-AO has excellent photocatalytic properties, which can reduce U(VI) to U(IV) quickly and selectively. The generated Z-type heterojunction promotes the reduction ability of photogenerated electrons, and obtains great selectivity to UO22+ (Uranyl ions) through the AO group. TiO2/CPAN-AO with π-electron conjugated structure broadens the spectral range through surface hybridization and prolongs the lifetime of photo-generated charges. Under the induction of light, the uranium extraction capacity of TiO2/CPAN-AO after 5 h of irradiation is about 2.38 g/g. TiO2/CPAN-AO is a catalyst with enhanced adsorption capacity, making it possible to extract uranium from large-scale natural seawater in the future.
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