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Promoted catalytic hydrodechlorination for deep degradation of chlorophenols over Rh-La/SiO2 catalyst
Jun Xiong1, Lei Tian1, Ruijie Cheng1
1Department of Pharmaceutical Engineering, School of Pharmacy and Key Laboratory of Basic Pharmacology of Guizhou Province, Zunyi Medical University, Zunyi, Guizhou 563000, China.
Abstract:
Deep degradation of chlorophenols (CPs) into safe and ecofriendly cyclohexanol during catalytic hydrodechlorination (HDC), shows important practical significance and attractive prospect in the treatment of wastewater containing chlorophenols. An efficient Rh-La/SiO2 catalyst was developed, by employing La as promoter. The presence of La in catalyst promoted catalytic performance of HDC significantly. Characterization results revealed that the interaction occurred between Rh and La in Rh-La/SiO2 catalyst. This interaction accompanied with the high dispersion and finely particle size of active Rh, and generation of abundant Rh sites neighboring La atom. Kinetic study illustrated that Rh-La(1:1)/SiO2 catalyst possessed the fastest kinetic constants, and minimized the apparent activation energies of 4-CP, phenol and cyclohexanone greatly. Complete degradation of 4-CP with a very high yield of cyclohexanol (> 98%) can be achieved at room temperature, making Rh-La(1:1)/SiO2 catalyst to be a promising candidate for deep degradation of CPs during HDC and other Rh catalyzed hydrogenation reactions.
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