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Updated: Oct 21, 2025

Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
Published on: May 16, 2014
A novel preparation of S-nZVI and its high efficient removal of Cr(VI) in aqueous solution
Hao Xu1, Mengxi Gao1, Xi Hu1
1College of Environmental Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China.
Abstract:
The chitosan-stabilized biochar supported S-nZVI (CS@BC/S-nZVI) composite with low aggregation and superior antioxidation were successfully synthesized by liquid-phase reduction method for the outstanding removal of Cr(VI) from wastewater and characterized by SEM, BET, FTIR, XRD, and XPS. The optimized synthesis parameters of CS@BC/S-nZVI were determined as a 0.14 molar ratio of S/Fe and a 0.25 mass ratio of BC/Fe. The CS@BC/S-nZVI possessed a specific surface area of 199.246 m2/g and an average pore size and pore volume of 1.186 nm and 0.272 cc/g. The CS@BC/S-nZVI could remain reductive activity after Cr(VI) removal and present a remarkable tolerance to the coexisting ions during Cr(VI) removal. The adsorption data were fitted well by the pseudo-second order model and the Langmuir model. The removal of Cr(VI) by CS@BC/S-nZVI was an exothermic process with prominent Cr(VI) removal capacities of 244.07 mg/g at 120 min and 221.84 mg/g at 15 min at 25 ℃. Further mechanism analysis proved that the binding of Cr(VI) to CS@BC/S-nZVI was mainly a synergistic effect of reduction and electrostatic attraction. Overall, these findings shed new light on the research of a novel S-nZVI compound and revealed the potential practical application of CS@BC/S-nZVI in the future heavy metal removal from wastewater.
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