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Updated: Oct 21, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
Modulating the relaxation dynamics via structural transition from a dinuclear dysprosium cluster to a nonanuclear
Peng Hu1,2, Ling-Hui Cao2, Ao-Gang Liu2
1Hubei Key Laboratory of Radiation Chemistry and Functional Materials, Non-power Nuclear Technology Collaborative Innovation Center, Hubei University of Science and Technology, Xianning 437100, People's Republic of China.
Abstract:
A dinuclear dysprosium cluster [Dy2(NO3)4(H2O)2(L)2]·2CH3CN was successfully prepared by employing HL (HL = 2,6-dimethoxyphenol) and Dy(NO3)3·6H2O in a mixture of CH3OH and CH3CN. The conversion of this Dy2 compound by reaction with additional deprotonated ligand generated a Dy9 cluster [Dy9(μ4-OH)2(μ3-OH)8(μ2-OCH3)4(NO3)8(H2O)8(L)4](OH)·2H2O with the well-known "diabolo" topology. Magnetic investigation revealed that both of the clusters exhibit typical SMM characteristics, and variable magnetic relaxation with the energy barrier changing from 217.87 K to 9.24 K along with the transition from a dinuclear dysprosium cluster to a nonanuclear one. Ab initio calculations further confirm the corresponding structure-activity relationships that originate the different magnetic behaviours. This design may afford a feasible strategy for modulating the magnetic relaxation dynamics of polynuclear systems.
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