Enhanced photocatalytic activity of Cu₂O for visible light-driven dye degradation by carbon quantum dots

Cuprous oxide (Cu₂O), a p-type semiconductor material, plays an important role in photocatalysis, which has narrower band gap (~2.1 eV), abundant availability, and low toxicity. However, the applications of Cu₂O are mainly restricted by its high recombination rate and low charge collection. Hence, it is of great significance to find an efficient method to improve the photocatalytic activity of Cu₂O. In this work, the CQDs-loaded Cu₂O nanocomposites (CQDs/Cu₂O) were successfully obtained via hydrothermal method. It was worth noting that the CQDs/Cu₂O nanocomposite displayed improved photocatalytic activity compared to that of pure Cu₂O with a lower dosage (25 mg) under visible light, which could completely degrade the methylene blue in 8 min. The recycling experiments also showed that the photocatalytic activity still remained up to 90% after 8 cycles. In addition to the photodegradation of methylene blue, the CQDs/Cu₂O nanocomposite also had an excellent antibacterial activity against Escherichia coli (100%, 30 min). These results demonstrated that introducing CQDs to Cu₂O was a feasible method to improve the photocatalytic performance of Cu₂O.