Generation of 2D nonlayered ferromagnetic VO₂(M) nanosheets induced by strain engineering of CO₂

Two-dimensional (2D) nonlayered ferromagnets displaying high Curie temperatures, sizable magnetic anisotropy levels, and large spin polarizations are emerging as promising 2D ferromagnetics. However, the difficulties in synthesizing 2D nonlayered intrinsic ferromagnets have largely limited their development. Herein, defect-rich 2D nonlayered VO₂(M) nanosheets have been fabricated by deploying straining engineering of CO₂ on the metal-insulator transition (MIT) of VO₂. Above T_MIT, the strong strain engineering of CO₂ in the R phase of VO₂ generated a very large number of atomic defects in its 3D crystal structure, and as a result facilitated conversion of the defective 3D network to 2D nanosheets along the c-axis. The as-prepared 2D defective VO₂(M) nanosheets displayed unique room-temperature ferromagnetism, attributed to the symmetry breaking triggered by the disordered atomic structure combined with the 3D-to-2D transformation.