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Improving Mechanical Properties of PLA/Starch Blends Using Masterbatch Containing Vegetable Oil Based Active
Bianka Nagy1, Norbert Miskolczi1, Zoltán Eller1
1Research Centre of Biochemical, Environmental and Chemical Engineering, MOL Department of Hydrocarbon & Coal Processing, Faculty of Engineering, University of Pannonia, H-8200 Veszprém, Hungary.
Polymers
|September 10, 2021
Summary
Vegetable oil additives enhance the compatibility of polylactic acid (PLA) and starch blends. These additives improved impact strength and other properties, especially in blends with higher starch content.
Area of Science:
- Polymer Science
- Materials Science
- Biocomposites
Background:
- Polylactic acid (PLA) and starch are biodegradable polymers with potential applications.
- Improving the compatibility between PLA and starch is crucial for developing advanced biocomposites.
- Vegetable oil-based additives offer a sustainable approach to modify polymer properties.
Purpose of the Study:
- To enhance the compatibility of polylactic acid (PLA) and starch blends using vegetable oil-based additives.
- To evaluate the effect of these additives on the mechanical properties of PLA/starch composites.
- To investigate the role of different vegetable oils and compatibilizers.
Main Methods:
- Preparation of PLA/starch blends with varying compositions (e.g., 70/30, 60/40, 50% starch).
- Incorporation of vegetable oil-based additives and a maleic anhydride-grafted PLA (PLA-g-MA) compatibilizer.
- Mechanical testing including tensile tests, Charpy impact strength, and elongation at break (conditioned and unconditioned).
- Scanning Electron Microscopy (SEM) for microstructural analysis.
Main Results:
- Charpy impact strength improved for 70/30 and 60/40 PLA/starch blends with vegetable oil additives.
- No significant improvement in impact strength was observed with PLA-g-MA.
- For the 50% starch sample, sunflower oil improved flexural modulus, while rapeseed oil enhanced impact strength and elongation at break.
- SEM images confirmed improved interfacial adhesion and compatibility between PLA and starch.
Conclusions:
- Vegetable oil-based additives are effective in enhancing the compatibility and mechanical properties of PLA/starch blends.
- Rapeseed and sunflower oils show specific benefits for different mechanical properties, particularly in high-starch content blends.
- These findings suggest a viable route for developing improved, sustainable biocomposites from PLA and starch.
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