Simple Method for the Fabrication of Multiple Superwetting Surfaces with Photoresponse

There have been many studies on special wetting surfaces, but most of them just stay superlyophobic in air or underwater. In this work, a membrane with photoresponse is fabricated by spraying hybrid particles of silicon and titanium dioxide. Under the combined action of hybrid particles and 1H,1H,2H,2H-perfluorodecyltrimethoxysilane, the prepared membrane is superhydrophobic in air. Because of the presence of titanium dioxide, the membrane can realize the transformation from superoleophilic underwater to superoleophobic underwater through UV irradiation and heating. Surprisingly, the membranes with superoleophobicity underwater are also superhydrophobic underoil. Thanks to this unique wettability transition, the prepared membrane can be applied to emulsion separation and fog harvesting. This is inspiring for the preparation and the multifunctional application of multiphase media superlyophobic surfaces.