Thiol Functionalised Supports for Controlled Metal Nanoparticle Formation for Improved C-C Coupling

The myriad applications of metal nanoparticle systems have individual demands on their size, shape and electronic states, demanding novel synthetic methods to optimise these properties. Herein we report our method of exploiting strong thiol-Pd binding as a precursor for forming small, uniform Pd nanoparticles on activation. We validate our approach with a range of characterisation techniques and contrast our design strategy with an analogous wetness impregnation method, showing the drastic improvements for catalytic C-C coupling. The presence of the thiol groups offers greater control over nanoparticle formation, particularly temperature resolution on activation, potentially allowing more targeted nanoparticle formation procedures.