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Published on: June 21, 2015
Uranium speciation control by uranyl sulfate and phosphate in tailings subject to a Sahelian climate, Cominak, Niger
Florian Lahrouch1, Benoit Baptiste1, Kathy Dardenne2
1Sorbonne Université, CNRS UMR7590, MNHN, IRD, Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), 4 Place Jussieu, Paris, F- 75005, France.
Abstract:
Long-term uranium mobility in tailings is an environmental management issue. The present study focuses on two U-enriched layers, surficial and buried 14.5 m, of the tailings pile of Cominak, Niger. The acidic and oxidizing conditions of the tailings pile combined with evapotranspiration cycles related to the Sahelian climate control U speciation. Uraninite, brannerite, and moluranite as well as uranophane are relict U phases. EXAFS spectroscopy, HR-XRD, and SEM/WDS highlight the major role of uranyl sulfate groups in uranium speciation. Uranyl phosphate neoformation in the buried layer (paleolayer) acts as an efficient trap for uranium.
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