Efficient detection of hazardous H₂S gas using multifaceted Co₃O₄/ZnO hollow nanostructures

The rapid increases in environmental hazardous gases have laid dangerous effects on human health. The detection of such pollutants gases is mandatory using various optimal techniques. In this paper, porous multifaceted Co₃O₄/ZnO nanostructures are synthesized by pyrolyzing sacrificial template of core-shell double zeolitic imidazolate frameworks (ZIFs) for gas sensing applications. The fabricated exhibit superior gas sensor response, high selectivity, fast response/recovery times, and remarkable stability and sensitivity to H₂S gas. In particular, the multifaceted Co₃O₄/ZnO nanostructures show a maximum response of 147 at 100 ppm of H₂S under optimum conditions. The remarkable gas sensing performances are mainly ascribed to high porosity, wide surface area multifaceted nanostructures, presence of heterojunctions and catalytic activity of ZnO and Co₃O₄, which are beneficial for H₂S gas sensors industry.