Polypyrrole/zeolite composite - A nanoadsorbent for reactive dyes removal from synthetic solution

Synthetic dyes are among the common pollutants in the ecosystem. In the present study, polypyrrole/zeolite (PPy/Ze) nanocomposite was prepared and subsequently assessed for the removal of Reactive blue (RB) and Reactive red (RR) from synthetic solution. The polymeric PPy/Ze composite was synthesized by chemical oxidation of pyrrole in the presence of zeolite. Electron microscopic images (transmission and scanning) indicate that PPy/Ze nanocomposite was spherical in shape with an average size of 40-80 nm. The characteristic pyrrole and zeolite Fourier transform infrared spectrum peaks (1542 cm^-1, 1463 cm^-1, 1156 cm^-1, 1054 cm^-1, 879 cm^-1 and 756 cm^-1) in the nanocomposite confirmed zeolite integration with polypyrrole. Experimental variables such as PPy/Ze nanocomposite dose, initial RB and RR concentration, reaction temperature and pH were optimized. The PPy/Ze nanocomposite adsorbed 86.2% of RB and 88.3% of RR from synthetic solution at optimal conditions (pH 9, initial RR or RB concentration, 75 mg/l; PPy/Ze dose, 1.8 g/l; and temperature, 50 °C). Freundlich isotherm model and pseudo-second-order kinetics showed better fit for both RB and RR removal from synthetic solution. X-ray diffractogram confirmed the amorphous nature of PPy/Ze nanocomposite and that it was not altered even after dye adsorption. Adsorption-desorption studies showed that the composite has satisfactory adsorption potential for four cycles. The results show that the PPy/Ze nanocomposite could be used for the removal of dyes from wastewaters.