Capacity-Limited Na-M foil Anode: toward Practical Applications of Na Metal Anode

The practical applications of Na metal anodes are severely plagued by unstable Na plating/stripping. Here the fabrication of Na-rich Na-M (M = Au, Sn, and In) alloy anodes is reported as promising alternatives to address this issue. As compared to metallic Na foil anodes, the alloy foils exhibit improved electrolyte/electrode interface and provide abundant sodiophilic sites for efficient Na plating, while the self-evolved porous Na-M structures accommodate volume variation on cycling. Among three alloy foils, the Na-Au system shows the most promising performance. Under practical conditions such as capacity-limited anodes (5 mAh cm^-2 ) and large stripping/plating capacity (1.0 mAh cm^-2 ), the Na_0.9 Au_0.1 anodes demonstrate stable plating/stripping over 350 h. The proof-of-concept full cells assembled with hard carbon or Prussian blue materials and this thin Na_0.9 Au_0.1 anode also have much elongated cycling life than for pristine Na metal anodes. These findings confirm that the rational design of Na-M alloy anodes can be a promising strategy to promote the development of Na metal batteries.