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Updated: Oct 20, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Recent advances in the synthesis and derivatization of N-heterocyclic carbene metal complexes
Vladislav A Voloshkin1, Nikolaos V Tzouras1, Steven P Nolan1
1Department of Chemistry and Center for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S-3), 9000 Ghent, Belgium. steven.nolan@ugent.be.
Abstract:
N-heterocyclic carbene (NHC) metal complexes have gained an incredible amount of attention in the course of the last two decades and have become indispensable as an intricate part of a plethora of applications. The areas of their synthesis and derivatization are constantly evolving and bring new, more sustainable, cost-effective and simpler approaches to the design of existing and next generation catalysts and materials. This article provides an overview of the latest developments, focusing on those which have appeared during the last two years.
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