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Published on: March 24, 2018
Two In-based organic-inorganic hybrid compounds with reversible phase transition derived from the order-disorder
Yin-Qiang Zhang1, Guan-Cheng Xu1, Min Li1
1State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, College of Chemistry, Xinjiang University, Urumqi, 830046, Xinjiang, PR China.
Abstract:
Solid-state phase transition materials have received extraordinary interest due to their rich physical properties, such as thermal, dielectric, and ferroelectric properties. Here, two In-based organic-inorganic hybrid compounds, (C6H5CH2CH2NH3)3[InBr5(H2O)] (1) and [(C3H7)4N][InCl4] (2), both display reversible phase transition and dielectric response. Differential scanning calorimetry measurements indicate that the phase transition temperatures (Tc) of 1 and 2 are 167 K and 351 K, respectively. Moreover, structural analyses disclose that the phase transition of 1 can be attributed to the order-disorder changes of phenethylammonium organic cations whereas the phase transition of 2 is caused by the order-disorder changes of [InCl4]- anions. The phase transitions of In-based organic-inorganic hybrid compounds can be driven by the order-disorder changes of cations or anions. Therefore, the system of In-based organic-inorganic hybrid compounds is very suitable for exploring organic-inorganic hybrid phase transition materials.
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