Acid leaching of LiCoO₂ enhanced by reducing agent. Model formulation and validation

In this work, a model has been formulated to describe the complex process of LiCoO₂ leaching through the participation of competing reactions in acid media including the effect of H₂O₂ as reducing agent. The model presented here describes the extraction of Li and Co in the presence and absence of H₂O₂, and it takes into account the different phenomena affecting the controlling mechanisms. In this context, the model predicts the swift from kinetic control to diffusion control. The model has been implemented and solved to simulate the leaching process. To validate the model and to estimate the model parameters, a set of 12 (in triplicate) extraction experiments were carried out varying the concentration of hydrochloric acid (within the range of 0.5-2.5 M) and hydrogen peroxide (range 0-0.6%v/v). The simulation results match fairly well with the experimental data for a wide range of conditions. Furthermore, the model can be used to predict results with different solid-liquid ratios as well as different acid and oxygen peroxide concentrations. This model could be used to design or optimize a LiCoO₂ extraction process facilitating the corresponding economical balance of the treatment.