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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Effect of polydispersity on the dynamics of active Brownian particles
Sameer Kumar1, Jay Prakash Singh1, Debaprasad Giri1
1Department of Physics, Indian Institute of Technology (BHU), Varanasi, Uttar Pradesh 221005, India.
Abstract:
We numerically study the dynamics and the phases of self-propelled disk-shaped particles of different sizes with soft repulsive potential in two dimensions. Size diversity is introduced by the polydispersity index (PDI) ε, which is the width of the uniform distribution of the particle's radius. The self-propulsion speed of the particles controls the activity v. We observe enhanced dynamics for large size diversity among the particles. We calculate the effective diffusion coefficient D_{eff} in the steady state. The system exhibits four distinct phases, jammed phase with small D_{eff} for small activity and liquid phase with enhanced D_{eff} for large activity. The number fluctuation is larger and smaller than the equilibrium limit in the liquid and jammed phases, respectively. Further, the jammed phase is of two types: solid jammed and liquid jammed for small and large PDI. Whereas the liquid phase is called motility induced phase separation (MIPS) liquid for small PDI and for large PDI, we find enhanced diffusivity and call it the pure liquid phase. The system is studied for three packing densities ϕ, and the response of the system for polydispersity is the same for all ϕ's. Our study can help understand the behavior of cells of various sizes in a tissue, artificial self-driven granular particles, or living organisms of different sizes in a dense environment.
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