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Published on: June 10, 2021
Visual Hg(II) sensing in aqueous solution via a new 2,5-Bis(4-pyridyl)thiazolo[5,4-d]thiazole-based fluorescence
Xin Li1, Deping Xiu1, Junjie Shi1
1National Demonstration Center for Experimental Chemistry Education, Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang, Hebei 050024, PR China.
Abstract:
A new fluorescence coordination polymer [Zn(Py2TTz)(5-OH-IPA)]n (1) (Py2TTz = 2,5-bis(4-pyridyl)thiazolo[5,4-d]thiazole, 5-OH-IPA = 5-hydroxyisophthalic acid dianion) was synthesized, which exhibited the characteristics of fluorescence quenching and bathochromic shift toward Hg(II) in aqueous solution at pH 7.00. Mechanism study showed that the interactions between Hg(II) ions and Py2TTz ligands in 1 were responsible for the fluorescence emission change. Thanks to the specific interactions between 1 and Hg(II), excellent selectivity was achieved both in aqueous solution and in solid test paper. The detection limit of 1 for Hg(II) sensing was 125.76 nmol L-1 and a linear rang was 1.00-10.00 μmol L-1. More importantly, satisfactory recovery and accuracy of 1 for Hg(II) sensing were also obtained in buffer-free real water samples.
