A Microporous MOF Constructed by Cross-Linking Helical Chains for Efficient Purification of Natural Gas and Ethylene

Natural gas (NG) and ethylene (C₂H₄) are two raw materials of significant value for manufacturing versatile fine chemicals and/or polymers, and thus the development of solid adsorbing agents such as metal-organic frameworks (MOFs) applied to their depuration is very crucial but remains highly challenging. In this research, we designed and synthesized a ligand containing mixed N and O coordination donors, which was solvothermally assembled with Cu(II) ions to generate a microporous MOF. X-ray crystallography revealed that the title MOF incorporates one-dimensional (1D) homochiral helical chains that are datively cross-linked to form open channels in the three-periodic coordination framework. Furthermore, the behaviors of C₁-C₂ hydrocarbons and carbon dioxide (CO₂) adsorbed in the title MOF were systematically investigated, revealing its promising potential for the purification of both NG and C₂H₄. At 109 kPa and 298 K, the C₂/methane (CH₄), CO₂/CH₄, and acetylene (C₂H₂)/C₂H₄ adsorption selectivities are impressive, reaching as high as 62.9, 28.6, and 3.5, respectively. This work represents a unique MOF based on cross-linked homochiral helical chains exhibiting dual-function separation potentials for NG and C₂H₄ purifications.