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Multifunctional Two-Dimensional Metal-Organic Frameworks for Radionuclide Sequestration and Detection.

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ACS Applied Materials & Interfaces
|September 20, 2021
PubMed
Summary

New porous coordination polymers containing lanthanides were synthesized. These materials show potential for uranyl ion capture and solid-state scintillation applications due to their unique structural and optical properties.

Keywords:
lanthanide luminescencemetal−organic frameworkspostsynthetic modificationradionuclide sequestrationtemperature-dependent luminescenceuranyl detection

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Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Coordination Chemistry

Background:

  • Porous coordination polymers (PCPs) offer tunable structures for various applications.
  • Lanthanide-based materials are explored for their unique optical and magnetic properties.

Purpose of the Study:

  • Synthesize and characterize novel lanthanide-containing PCPs.
  • Investigate the structural, thermal, and optical properties of these materials.
  • Evaluate their potential for uranyl ion capture and X-ray scintillation.

Main Methods:

  • Hydrothermal synthesis of lanthanide coordination polymers.
  • Structural characterization using powder and single-crystal X-ray diffraction.
  • Analysis of optical properties via absorbance, fluorescence, and lifetime spectroscopies.
  • Assessment of uranyl ion adsorption and X-ray induced luminescence.

Main Results:

  • Two new PCPs, [Ln₂(bpdc)₆(phen)₂]·nH₂O (1) and [Ln₂(bpdc)₆(terpy)₂]·3H₂O (2), were synthesized and characterized.
  • Compound 1 exhibits a 2D framework, while compound 2 forms a 3D framework.
  • Materials are stable in aqueous media (pH 3-10) and thermally stable up to ~400 °C.
  • Ligand removal in compound 1 enhances surface area and pore volume.
  • Eu³⁺-containing compound 1 effectively captures uranyl ions and exhibits luminescence.
  • Both compounds with Eu³⁺ show red emission under X-ray irradiation, indicating scintillation potential.

Conclusions:

  • The synthesized lanthanide-containing PCPs possess robust structures and tunable properties.
  • Compound 1 demonstrates promise for selective uranyl ion detection and removal.
  • These materials are viable candidates for solid-state scintillation detectors.