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Updated: Oct 19, 2025
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Improving the single-molecule magnet properties of two pentagonal bipyramidal Dy3+ compounds by the introduction of
Li Zhu1, Yubao Dong1, Bing Yin2
1Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China. dfli@mail.ccnu.edu.cn.
Abstract:
Two mononuclear Dy3+ compounds [Dy(bmbpen-F)X] (X = Cl, 1; Br, 2) with a pentagonal bipyramidal (PBP) geometry were obtained from N,N'-bis-(5-methyl-2-hydroxybenzyl)-N,N'-bis(5-fluoro-2-methylpyridyl)ethylenediamine (H2bmbpen-F) and dysprosium halides. The magnetic anisotropy and single-molecule magnet (SMM) behavior of these PBP compounds were regulated by introducing both electron-withdrawing F atoms into the equatorial pyridine rings and electron-donating -CH3 groups into the axial phenolic hydroxyl rings. The results of magnetic characterization show that 1 and 2 exhibit single molecule magnet behavior with magnetization reversal barriers of 990(13) and 1189(16) K under a zero dc external field and magnetic hysteresis loops up to 26 K and 36 K, respectively. The results of ab initio calculations are consistent with the experimental observations, confirming that the simultaneous introduction of electron-withdrawing groups into the equatorial positions and electron-donating groups into the axial positions can lead to PBP Dy-SMMs with improved properties.
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