Sunlight-promoted photodegradation of Congo red by cadmium-sulfide decorated graphene aerogel

Herein, a simpler-viable methodology for the surface decoration of pear fruit derived graphene aerogel (GA) via cadmium sulfide (CdS) has been presented. GA can be easily synthesized from bio-mass, which provide an economic advantage. Surface decoration via CdS imparts photocatalytic activities in functionalized graphene aerogels (f-GA). CdS-f-GA is being explored here as a photocatalyst for the degradation of a toxic azo dye named Congo red in the presence of sunlight. The rate and mechanism associated with photodegradation were analyzed by performing kinetics and radical trap-based quenching experiments. Nuclear magnetic resonance and fourier transform infrared spectroscopy analyses of the control and photodegraded products were performed to ensure the degradation of the organic framework of Congo red. Additionally, the real-life applicability of CdS-f-GA was also analyzed by degrading the dye in different types of industrial samples (via the method of external spiking), which can advance its practical relevance.