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Updated: Oct 19, 2025

Quantitative Atomic-Site Analysis of Functional Dopants/Point Defects in Crystalline Materials by Electron-Channeling-Enhanced Microanalysis
Published on: May 10, 2021
Bonding analysis in ytterbium(II) distannyl and related tetryls
Peter M Chapple1, Julien Cartron1, Ghanem Hamdoun2
1Univ Rennes, CNRS, ISCR-UMR 6226, 35000 Rennes, France. yann.sarazin@univ-rennes1.fr.
Abstract:
The syntheses of the ytterbium(II) distannyl [Yb{Sn(SiMe3)3}2·(thf)4] (Yb-Sn) and of its digermyl analogue [Yb{Ge(SiMe3)3}2·(thf)3] (Yb-Ge) are presented. The compounds were characterised by multinuclear high-resolution solution NMR spectroscopy, including 171Yb NMR, and by X-ray diffraction crystallography. The bonding and electronic properties of the two complexes, along with those of the known ytterbium(II) disilyl derivative [Yb{Si(SiMe3)3}2·(thf)3] (Yb-Si) and those of the congeneric calcium distannyl [Ca{Sn(SiMe3)3}2·(thf)4] (Ca-Sn), were investigated in detail by DFT calculations. This analysis points at a primarily ionic Yb-tetrel bonding, with a small covalent contribution, attributed principally to the 5d(Yb) participation. This weak covalent character is found to be larger for the distannyl Yb-Sn than for its lighter Si- and Ge-derivatives. The covalent component is also found to be greater in Yb-Sn than in Ca-Sn, due to the availability of the 5d(Yb) orbitals for bonding.
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