Application of polysaccharide biopolymers as natural adsorbent in sample preparation

Preparing samples for analyses is perhaps the most important part to analyses. The varied functional groups present on the surface of biopolymers bestow them appropriate adsorption properties. Properties like biocompatibility, biodegradability, presence of different surface functional group, high porosity, considerable absorption capacity for water, the potential for modification, etc. turn biopolymers to promising candidates for varied applications. In addition, one of the most important parts of determination of an analyte in a matrix is sample preparation step and the efficiency of this step in solid phase extraction methods is largely dependent on the type of adsorbent used. Due to the unique properties of biopolymers they are considered an appropriate choice for using as sorbent in sample preparation methods that use from a solid adsorbent. Many review articles have been published on the application of diverse adsorbents in sample preparation methods, however despite the numerous advantages of biopolymers mentioned; review articles in this field are very few. Thus, in this paper we review the reports in different areas of sample preparation that use polysaccharides-based biopolymers as sorbents for extraction and determination of diverse organic and inorganic analytes.