Considering photocatalytic activity of Cu²⁺/biochar-doped TiO₂ using corn straw as sacrificial agent in water...

In this paper, a simple one-pot thermal synthesis method was used to successfully prepare Cu²⁺/biochar-doped TiO₂ composite catalytic materials. The photocatalytic hydrogen production performance of the composites under different environmental conditions (dark, solar, and visible light irradiation) was analyzed in a biomass photocatalytic system using a corn straw suspension as a sacrificial agent. The Cu²⁺/biochar-doped TiO₂ materials were characterized by SEM, TEM, XRD, FT-IR, XPS, and UV analysis. The photoelectric properties of the Cu²⁺/biochar-doped TiO₂ composites were also analyzed, and the charge separation mechanism of photogenerated carriers under different environmental conditions was investigated. Compared with pure TiO₂, the hydrogen production rate of Cu²⁺/biochar-doped TiO₂ is 23.6 times higher under visible light irradiation and 16.8 times higher under simulated solar irradiation. Using density functional theory, a crystal structure model of Cu²⁺/biochar-doped TiO₂ was established to analyze its energy band structure and density of states. An analysis of the mechanism shows that under simulated sunlight irradiation, the synergistic effect of the TiO₂ doped with Cu²⁺ and biochar causes the formation of a potential Schottky heterojunction on the surface and induces interfacial charge transfer. Furthermore, under visible light irradiation, the photocatalytic production of hydrogen by the Cu²⁺/biochar-doped TiO₂ composite is mainly due to the surface plasmon resonance mechanism of Cu ion-doped TiO₂.