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Improving the Efficiency of Organic Solar Cells by Introducing Perylene Diimide Derivative as Third Component and
Hao Lu1, Juncheng Liu1, Yahui Liu2
1Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing, 100875, P. R. China.
Abstract:
A perylene diimide (PDI) derivative was used as the third component to prepare high-efficiency ternary organic solar cells (OSCs). PDI derivatives usually bear a wide bandgap and a long exciton diffusion length, which could be helpful to promote the device efficiency and still retain a high open-circuit voltage (Voc ). Compared with the binary OSC, the photovoltaic performance improved. Further changing the method for preparing the processing solutions from dissolving the polymer donor and small-molecule acceptor ITTC together to dissolving them individually, molecular packing in the deposited active layer could be adjusted and the short-circuit current density could be increased. As a result, the final device efficiency in such OSCs achieved 12.29 % power conversion efficiency (PCE) with a high Voc of 0.93 V. When using the PDI derivative as the third component to D18 : BTP-eC9-based OSCs, a high PCE of 17.38 % was obtained, which is the best one among photovoltaic devices employing PDI derivatives.
