Related Experiment Video
Updated: Oct 18, 2025
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Stabilization of dichalcogenide ligands in the coordination sphere of a ruthenium system
Koushik Saha1, Sourav Gayen1, Urminder Kaur1
1Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India. sghosh@iitm.ac.in.
Abstract:
The synthesis, structure and electronic properties of tetraruthenium dichalcogenide complexes displaying the exclusive coordination mode of dichalcogenide ligands have been discussed. The reactions of Li[BH2E3] (E = S or Se) with [ClRu(μ-Cl)(p-cymene)]2 (p-cymene = η6-{p-C6H4(iPr)Me}) at room temperature yielded tetrametallic dichalcogenide complexes [{Ru2Cl2(p-cymene)2}2(μ4,η2-E2)], 1-2 (E = S (1) and Se (2)). The solid-state X-ray structure of 1 shows that two {(p-cymene)RuCl}2 moieties are bridged by a S-S bond. In addition to 2, the reaction of Li[BH2Se3] with [ClRu(μ-Cl)(p-cymene)]2 also yielded a mononuclear tris-homocubane analogue [Ru(p-cymene){Se7(BH)3}] (3) which is an analogue of 1,3,3-tris-homocubane and possesses D3 symmetry. In order to isolate the Cp* analogue of 1, the reaction of [Cp*Ru(μ-Cl)Cl]2 with Li[BH2S3] was carried out, which led to the formation of bis/tris-homocubane derivatives [(Cp*Ru)2{μ-S(BH)2}] (n = 7 (4) and 6 (5)) along with the formation of ruthenium disulfide complexes [(RuCp*)2(μ,η2:η2-S2)(μ,η1:η1-S2)] and [(RuCp*)2(μ-SBHS-κ1B:κ2S:κ2S)(μ,η1:η1-S2)]. Complexes 1-5 have been characterized by multi-nuclear NMR, IR, UV-vis spectroscopy, and mass spectrometry and their molecular formulations (except 2) have been determined by single crystal X-ray crystallography. Furthermore, DFT calculations were performed that rationalize the stabilization of the dichalcogenide units (E22-) by the tetrametallic systems in 1-2.
More Related Videos
10:52Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
Published on: July 27, 2022
10:39Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Related Concept Videos
02:51Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
01:09Complexation Equilibria: Factors Influencing Stability of Complexes
01:19Complexation Equilibria: The Chelate Effect
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
02:42Valence Bond Theory
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...