Laser-Engineered Superhydrophobic Polydimethylsiloxane for Highly Efficient Water Manipulation

Low-cost, high-quality, and large-area superhydrophobic surfaces are in high demand. This study demonstrates laser-engineered polydimethylsiloxane (PDMS) as a platform for versatile and highly efficient water manipulation. The fabrication process consists of two steps: patterning PDMS with arrayed microlenses and laser pulse scanning. The obtained PDMS is superhydrophobic and exhibits excellent chemical resistance, UV stability, pressure robustness, and substantial mechanical durability. Notably, there is no significant change in the water contact angles after storage in air for 14 months. Microstructural analysis revealed that the sample contained stable nanostructured inorganics such as crystalline silicon, silicon carbide, and sp³-like carbon. The superhydrophobic surface was demonstrated to have versatile and wide applications in oil/water separation and water collection.