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Updated: Oct 18, 2025

Electrochemically and Bioelectrochemically Induced Ammonium Recovery
Published on: January 22, 2015
Atomic-dispersed copper simultaneously achieve high-efficiency removal and high-value-added conversion to ammonia of
Xue Zhao1, Xue Li2, Haibo Zhang3
1Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Kunming 650504, China; College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
Abstract:
Environmentally friendly electrochemical reduction pathways from NO3- to NH3 or N2 have provided feasible strategy into the green production of ammonia or the treatment of nitrate wastewater. Here, we anchored single-atom Cu with boron carbon nitride on carbon nanotube (BCN@Cu/CNT), and achieved the efficient operation of electrochemical nitrate reduction reaction (NIRR). BCN@Cu/CNT can efficiently catalyze the selective conversion of high-concentration nitrate into high-value-added ammonia, where the ammonia yield rate and Faradaic efficiency are as high as 172,226.5 μg h-1 mgcat.-1 and 95.32% (at -0.6 V), respectively. BCN@Cu/CNT also shows the ability to efficiently remove low-concentration nitrates in sewage. Specifically, here only takes 5 h to nearly 100% (99.32%) eliminate NO3- (50 mg L-1) in sewage without any residual NO2-. The excellent catalytic activity and physicochemical stability of BCN@Cu/CNT for NIRR suggest the promising industrial application prospects, including the green production of ammonia and the purification of nitrate wastewater.
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